“The carbon–fluorine (C–F) bond is one of the strongest in organic chemistry, requiring huge amounts of energy to break down, at huge expense. But now two papers in Nature describe two low-energy ways to overcome the C–F bond.

Both methods combine a catalyst with some relatively simple chemistry driven by the energy of visible light. In each case, the catalyst absorbs light that then triggers a reaction.

Chemist Garret Miyake at Colorado State University in Fort Collins and his colleagues use this absorbed energy to reduce the C–F bond to carbon–hydrogen — albeit not in Teflon. Yan-Biao Kang, a chemist at the University of Science and Technology of China in Hefei, and his colleagues uses this energy to break the bond and the overall molecule down to smaller constituent parts, in temperatures as low as 40 °C. Both papers, without doubt, mark a major step forward.

Important next steps include using these ideas in real-world settings, for example to develop catalysts that work in waste water or that can be used to clean up PFAS in contaminated soils. If a method can be adapted so that it is powered by sunlight, that would be of huge benefit.”

From Nature.